No. The number of users added to the program does not affect the number of user licenses available. The number of user licenses is the maximum number of users to be logged into the database at one time.

For example, if there are 10 users for The Raiser's Edge but the number of user licenses available is 4, this means that only 4 out of 10 users are able to be logged into The Raiser's Edge at the same time.